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Beilstein J. Org. Chem. 2022, 18, 746–753, doi:10.3762/bjoc.18.75
Graphical Abstract
Figure 1: Highly reactive dienophiles.
Figure 2: Dibromide substrates and product 12.
Scheme 1: Mechanochemical reaction of 10 with anthracene.
Figure 3: Scope of the Zn/Cu reaction with dibromide 10 (dienes are colored in red).
Scheme 2: Mechanochemical reaction of 11 with furan.
Scheme 3: Reactivity of bicyclo[2.2.2] dibromide 42 with dienes.